Conformation of isotactic polypentene-1
β Scribed by Moraglio, G. ;Brzezinski, J.
- Publisher
- Wiley (John Wiley & Sons)
- Year
- 1964
- Tongue
- English
- Weight
- 119 KB
- Volume
- 2
- Category
- Article
- ISSN
- 0449-2986
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π SIMILAR VOLUMES
Minimum potential energy helical conformations for a family of four isotactic polyacetaldehydes have been determined. Our results indicate that all of the polymers form irrational helices. Comparisons have been made with the reported structures for two of these stereoregular polymers based on earlie
Oriented specimens of isotactic cis-l,4-poly(3-methyl-l,3-pentadiene) exhibit two crystalline modifications characterized, respectively, by the expected two-fobd helical conformation with a fiber repeat of 8,02 A and by a three-fold helix with c = 9,97 A. The latter highly contracted structure is pr
## Abstract In order to obtain information about a possible helixβcoil transition of isotactic polystyrene (iβPS) at 80Β°C in toluene, as has been reported in other solvents, solution properties were examined at temperatures between 10 and 110Β°C. Use was made of viscometry, highβresolution nuclear m