Conformation, environment and reactivity of radicals in copolymerization of methyl methacrylate/ethylene glycol dimethacrylate
β Scribed by Y. Tian; S. Zhu; A.E. Hamielec; D.B. Fulton; D.R. Eaton
- Publisher
- Elsevier Science
- Year
- 1992
- Tongue
- English
- Weight
- 582 KB
- Volume
- 33
- Category
- Article
- ISSN
- 0032-3861
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The steady-state fluorescence technique was used to study the free-radical crosslinking copolymerization of methyl methacrylate and ethylene glycol dimethacrylate in the absence and presence of toluene at 75Β°C. A sol-gel phase transition was observed and monitored by an excited aromatic molecule dur
The reaction kinetics and gelation behavior in atom transfer radical polymerization (ATRP), reversible addition-fragmentation chain transfer (RAFT), and conventional free radical copolymerizations (FRP) of oligo(ethylene glycol) methyl ether methacrylate (OEGMEMA) and oligo(ethylene glycol) dimethac