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Conformation and Stability of Adducts of Cyclic Ammines with Water: Free Jet Absorption Millimeter-Wave Spectrum of Pyrrolidine−Water

✍ Scribed by Caminati, Walther; Dell'Erba, Adele; Maccaferri, Gianni; Favero, Paolo G.


Book ID
125898150
Publisher
American Chemical Society
Year
1998
Tongue
English
Weight
50 KB
Volume
120
Category
Article
ISSN
0002-7863

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Free Jet Absorption Millimeter Wave Spec
✍ Walther Caminati; Adele Dell' Erba; Gianni Maccaferri; Paolo G. Favero 📂 Article 📅 1998 🏛 Elsevier Science 🌐 English ⚖ 91 KB

The equatorial conformer of pyrrolidine has been discovered while investigating the rotational free jet spectrum of the pyrrolidine-water adduct. It is more stable than the axial species, previously assigned with conventional microwave spectroscopy (W. Caminati, H. Oberhammer, G.