From the leaves and seeds of Podocarpus m, ZOLI. et MORITZI (l), we have isolated three nordlterpenoid dilactonea, nagilaotone A, B and C, and a bisnorditerpenoid dilactone, nagilactone D (TABLE I), and established their structures as I, II, III and IV: The evidence is provided in this paper. TABLE
Configurations of nagilactones C and D
✍ Scribed by Shô Itô; Mitsuaki Kodama; Makoto Sunagawa; Hinako Honma; Toshio Takahashi
- Book ID
- 104239642
- Publisher
- Elsevier Science
- Year
- 1969
- Tongue
- French
- Weight
- 230 KB
- Volume
- 10
- Category
- Article
- ISSN
- 0040-4039
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✦ Synopsis
In a previous paper (l), the Osaka group &scribed the isolation from Podocorous w Zori et Moritzi and determination of the planer structures of four nor-and bisnor-diterpenic lactones, nagilactones A, 6, C and D. Since the nagiloctones A and C, as well as inumakilactones, were also isolated from the seeds and the leaves of L macroohvllus D. Don. by the Se&i and the Tokyo groups (2), we have collaborated in the determination of the stereochemistry of these compounds, and present here evidence which permits the crssignment of structure I and II with absolute configuration for nagilactones C and D, respectively.
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