Configurational Stability and Transfer of Stereochemical Information in the Reactions of Enantioenriched Organolithium Reagents
β Scribed by Amit Basu; S. Thayumanavan
- Publisher
- John Wiley and Sons
- Year
- 2002
- Tongue
- English
- Weight
- 468 KB
- Volume
- 41
- Category
- Article
- ISSN
- 0044-8249
No coin nor oath required. For personal study only.
π SIMILAR VOLUMES
The title compound, 6, was generated by stereospecific chlorides leads to partial racemization due to competing front face attack. Semiempirical calculations point to an increased deprotonation of the optically active carbamate 5 with secbutyllithium/TMEDA and proved to be configuratively degree of
AgC 6 F 5 is directly and quantitatively formed from room temperature reactions of AgF and Me 3 SiC 6 F 5 in N-donor solvents, particularly EtCN. Solutions of AgC 6 F 5 prepared by this method exhibit excellent oxidative properties in reactions with a variety of groups 12 to 16 elements giving the c