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Configurational Multiplicity of Porphyrin π Cation Radicals: Nickel π−π Dimers

✍ Scribed by Barkigia, Kathleen M.; Renner, Mark W.; Fajer, Jack


Book ID
126419234
Publisher
American Chemical Society
Year
1997
Tongue
English
Weight
251 KB
Volume
101
Category
Article
ISSN
0022-3654

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## Abstract **π–π assisted**: Photoinduced electron transfer from cofacial porphyrin dimers to electron acceptors is prominently accelerated, whereas the back electron transfer is decelerated, relative to the corresponding porphyrin monomer (see figure).magnified image The radical cation of zinc t