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Configurational Correlation of Alcohols by Asymmetric Synthesis of Sulfinate Esters1

โœ Scribed by Green, Mark M.; Axelrod, Michael; Mislow, Kurt


Book ID
111960769
Publisher
American Chemical Society
Year
1966
Tongue
English
Weight
271 KB
Volume
88
Category
Article
ISSN
0002-7863

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## Reaction of pinanediol boronates with ( I ,I -dichlo-roethy1)lithium generated in situ at -78ยฐC followed by reawangemenf o f the resulting borate complex 2 s in the presence of zinc chloride at 25ยฐC has resulted in chirally biased insertion of the I -chloroethyl group into the carbon-boron bond