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Configurational characterization of the 1-(trimethylsilyl)cyclopropyl radical

✍ Scribed by Leo A. Paquette; Manfred Hoppe; Linda J. Johnston; Keith U. Ingold


Book ID
104219531
Publisher
Elsevier Science
Year
1986
Tongue
French
Weight
212 KB
Volume
27
Category
Article
ISSN
0040-4039

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πŸ“œ SIMILAR VOLUMES


Configurational stability of cyclopropyl
✍ Gernot Boche; Dieter R. Schneider πŸ“‚ Article πŸ“… 1978 πŸ› Elsevier Science 🌐 French βš– 203 KB

Cyclopropyl radicals normally undergo complete thermodynamic equilibration of configuration before they react, e.g., with bromine in the Hunsdiecker reaction'. Incomplete equilibration is normally due to steric or cage effectsa, and to surface effects when cyclopropyl halides are reduced with metals

Structure of the 1-cyclobutyl and 1-cycl
✍ M. Kikuchi; N. Leray; J. Roncin πŸ“‚ Article πŸ“… 1975 πŸ› Elsevier Science 🌐 English βš– 243 KB

Determination of the carbon 13 ESR coupling constants for the l-cyclobutyl and l-cyclopropyl carboxylic radicals shows that, even for cyclopropyl, the substitution of Z-I H, ritom by s COOH group leads to a stabilization of the x struc- ture.