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Configuration of the 3,12 double bond of roquefortine

✍ Scribed by Scott, Peter M.; Polonsky, Judith; Merrien, Marie Annick

Book ID
126250489
Publisher
American Chemical Society
Year
1979
Tongue
English
Weight
246 KB
Volume
27
Category
Article
ISSN
0021-8561

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πŸ“œ SIMILAR VOLUMES

Relative and Absolute Configuration of t
Relative and Absolute Configuration of the 3,12-Dihydroxypalmitic Acids
✍ Jakob, Barbara ;Gerlach, Hans πŸ“‚ Article πŸ“… 1996 πŸ› John Wiley and Sons 🌐 English βš– 895 KB

## Abstract The relative and absolute configuration of (+)‐3,12‐dihydroxypalmitic acid, a constituent of the __Ipomea operculata__ M. resin, has been determined by synthesis. Dimethyl L‐malate was converted via (__S__)‐(+)‐1 into the oxirane (__S__)‐(‐)‐2. Reaction of (‐)‐2 with the Grignard reagen