✦ LIBER ✦

Conductometric and viscometric investigation of poly(N-vinylimidazole)-metal ion complex formation

✍ Scribed by Nursel Pekel; Alý Güner; Olgun Güven

Publisher: John Wiley and Sons
Year: 2002
Tongue: English
Weight: 200 KB
Volume: 85
Category: Article
ISSN: 0021-8995
DOI: 10.1002/app.10613

No coin nor oath required. For personal study only.

✦ Synopsis

Abstract

The complexation of copper (Cu^2+^), cobalt (Co^2+^), and cadmium (Cd^2+^) ions with poly(N‐vinylimidazole) (PVIm) and its protonated form in aqueous solution was studied conductometrically and viscometrically. From the conductometric and viscometric curves, it was found that four imidazole units were coordinated with one metal ion in the complex systems. Both studies showed that the complex formation tendency decreased in the following order: Cu^2+^ > Co^2+^ > Cd^2+^. Complex properties of metal ions with imidazole group were explained by referring to Pearson's treatment, as hard and soft acids and bases. © 2002 Wiley Periodicals, Inc. J Appl Polym Sci 85: 376–384, 2002

📜 SIMILAR VOLUMES

Metal ion binding properties of poly(N-v

Metal ion binding properties of poly(N-vinylimidazole) hydrogels

✍ Bernabé L. Rivas; Hernán A. Maturana; M. Jesús Molina; M. Rosa Gómez-Aantón; Iné 📂 Article 📅 1998 🏛 John Wiley and Sons 🌐 English ⚖ 217 KB 👁 2 views

The ability of poly(N-vinylimidazole) hydrogels to bind Cu(II), Co(II), Ni(II), Zn(II), Cd(II), Pb(II), Hg(II), Na(I) and Ca(II) cations, as well as uranyl, vanadium, rhenium, and molybdenum complexes, was studied by a batch equilibrium procedure using atomic absorption spectroscopy and UV-Vis spect

Applied macroinorganics. II. Protonation

Applied macroinorganics. II. Protonation and heavy metal ions complex-formation behavior of three crosslinked resins of poly(amido-amine) structure

✍ P. Ferruti; C. Bertoglio Riolo; T. Soldi; M. Pesavento; R. Barbucci; M. C. Beni; 📂 Article 📅 1982 🏛 John Wiley and Sons 🌐 English ⚖ 393 KB 👁 2 views

Formation of Ternary Complexes by Coordi

Formation of Ternary Complexes by Coordination of (Diethylenetriamine)Platinum(II) to N1 or N7 of the Adenine Moiety of the Antiviral Nucleotide Analogue 9-[2-(Phosphonomethoxy)ethyl]adenine (PMEA): Comparison of the Acid–Base and Metal-Ion-Binding Properties of PMEA, (Dien)Pt(PMEA-N1), and (Dien)Pt(PMEA-N7)

✍ Gunnar Kampf; Marc Sven Lüth; Larisa E. Kapinos; Jens Müller; Antonín Holý; Bern 📂 Article 📅 2001 🏛 John Wiley and Sons 🌐 English ⚖ 185 KB 👁 2 views