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Conductivity of highly concentrated aqueous electrolyte solutions: NH4NO3 + H2O + LiNO3 system

✍ Scribed by R.C. Sharma; H.C. Gaur

Publisher
Elsevier Science
Year
1976
Tongue
English
Weight
269 KB
Volume
21
Category
Article
ISSN
0013-4686

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✦ Synopsis

Abslract-Conductivity of ammonium nitrate + water (2moles per mole NH,NO,) + lithium nitrate mixtures containing up to 0.225 stoichiometric mole fraction of lithium nitrate, at the temperatures ranging between 295-345 K, has been measured. At a given composition the variation of conductivity with temperature could be expresed by the equation, rc=A+BT Where A and B are empirical constants. Conductivityamposition isotherms are non-linear. indicating the change in the ordering tendency of the system.

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Abatraet-Conductivity of molten Mg(NOs)2. 6Hz0 + NH,NO, system containing up to 80 mole percent of the latter was measured in the temperature range 320-400K. Temperature dependence of conductivity exhibited Arrhenian behaviour. Conductivity-composition isotherms Were non-linear indicating weak order