Condensation of hexafluoroacetone with α,β-unsaturated carbonyl compounds
✍ Scribed by A. V. Fokin; A. F. Kolomiets; A. A. Krolevets
- Book ID
- 112439247
- Publisher
- Springer
- Year
- 1978
- Tongue
- English
- Weight
- 54 KB
- Volume
- 27
- Category
- Article
- ISSN
- 1573-9171
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Lithium diorganocuprates are now widely used in conjugate additions to a,a-unsaturated car-bony1 compounds' and in coupling reactions with alkyl halides2, allyli~acetates~, and other compounds possessing good leaving groups. Here we report a new reaction of lithium dialkylcuprates which is formally
## Abstract Except from 1,4,9,10‐anthracenetetrols, 9,10‐anthrahydroquinones (derived from the quinones **5a** and **18**– **21**) react with unhindered Michael acceptors such as acrylate, acrylonitrile, acrylaldehyde, and methyl vinyl ketone with addition at C‐9 or C‐10 to yield anthrones. The dir