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Condensation of 2-(acetamido)cyclohexanone with malononitrile

✍ Scribed by V. I. Shvedov; M. V. Mezentseva; L. B. Altukhova; A. N. Grinev


Book ID
112326951
Publisher
Springer US
Year
1974
Tongue
English
Weight
211 KB
Volume
10
Category
Article
ISSN
0009-3122

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Structure of the 2:2 condensation produc
✍ Wayland E. Noland; Richard J. Sundberg πŸ“‚ Article πŸ“… 1962 πŸ› Elsevier Science 🌐 French βš– 277 KB

NITROMETHANE and cyclohexanone condense in refluxing solution in the presence of secondary amines to a colorless 212 product C14H20N203 (I), m.p. 270-271' (sublimes). 2,3' Secondary amines used as catalysts include piperidine4 (8-14,3 24s5 yield), piperazine (47$),5 pyrrolidine (23%),5 morpholine (2