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Concurrent Synthesis of Dimethyl Carbonate and Ethylene Glycol via Transesterification of Ethylene Carbonate and Methanol Using Smectite Catalysts Containing Mg and/or Ni

โœ Scribed by Bhalchandra M. Bhanage; Shin-ichiro Fujita; Yanfeng He; Yutaka Ikushima; Masayuki Shirai; Kazuo Torii; Masahiko Arai


Book ID
110403337
Publisher
Springer US
Year
2002
Tongue
English
Weight
128 KB
Volume
83
Category
Article
ISSN
1011-372X

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Transesterification of urea and ethylene
โœ Bhanage, Bhalchandra M.; Fujita, Shin-ichiro; Ikushima, Yutaka; Arai, Masahiko ๐Ÿ“‚ Article ๐Ÿ“… 2003 ๐Ÿ› Royal Society of Chemistry ๐ŸŒ English โš– 86 KB

Two-step synthesis of dimethyl carbonate (DMC) from urea has been investigated with various solid catalysts. The first step involves reaction of urea with ethylene glycol (EG) to form ethylene carbonate (EC) and the second step transesterification of EC formed with methanol to give DMC and EG. It ha