Concise total synthesis of (±)-palominol and (±)-dolabellatrienone via a dianion-accelerated oxy-cope rearrangement
✍ Scribed by E.J. Corey; Robert S. Kania
- Publisher
- Elsevier Science
- Year
- 1998
- Tongue
- French
- Weight
- 211 KB
- Volume
- 39
- Category
- Article
- ISSN
- 0040-4039
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## Abstract ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 200 leading journals. To access a ChemInform Abstract, please click on HTML or PDF.
## Abstract ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 200 leading journals. To access a ChemInform Abstract, please click on HTML or PDF.
Key steps in this approach to umaryllidaceae alkaloids containing oxidation at the R-position of the pyrroline ring are (a) copper(H)-promoted rearrangement of aminocyclopentanol 11 to afford the 3-silylhydroindole 12, and (b) oxidation of 12 by the general procedures of Kumada and Fleming to give t