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Concise total synthesis of (±)-aspidospermidine via an oxidative Hosomi–Sakurai process

✍ Scribed by Sabot, Cyrille; Guérard, Kimiaka C.; Canesi, Sylvain

Book ID
120499162
Publisher
Royal Society of Chemistry
Year
2009
Tongue
English
Weight
523 KB
Volume
20
Category
Article
ISSN
1359-7345

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Efficient formal synthesis of (±)-axamid
Efficient formal synthesis of (±)-axamide-1 and (±)-axisonitrile-1 via an intramolecular Hosomi–Sakurai reaction
✍ Kazunori Takahashi; Kentaro Takeda; Toshio Honda 📂 Article 📅 2010 🏛 Elsevier Science 🌐 French ⚖ 492 KB

A formal synthesis of (±)-axamide-1 and (±)-axisonitrile-1 was achieved by using an intramolecular Hosomi-Sakurai reaction of the allylsilane derivative, as a key step, in which [(3-but-3-en-1-yl-3-methylcyclohex-1-en-1-yl)methyl](trimethyl)silane was transformed to a bicyclic compound possessing a