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Concise Synthesis of Anhydrovinblastine from Leurosine

✍ Scribed by Hardouin, Christophe; Doris, Eric; Rousseau, Bernard; Mioskowski, Charles

Book ID
126822567
Publisher
American Chemical Society
Year
2002
Tongue
English
Weight
47 KB
Volume
4
Category
Article
ISSN
1523-7060

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Preliminary investigations have led to the discovery that ferric ion can couple catharanthine and vindoline, in aqueous acidic media, to produce 3',4'-anhydrovinblastine as the major product. A conversion of 77% couldbe realized under optimized'conditions. Alkaloids derived from plants of the Apocyn