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Concise Approach to the Carbocyclic Core of the Naturally Occurring Sphingomyelinase Inhibitor Scyphostatin

✍ Scribed by Mehta, Goverdhan; Modugu, Nagi Reddy


Book ID
120174490
Publisher
American Chemical Society
Year
2013
Tongue
English
Weight
513 KB
Volume
78
Category
Article
ISSN
0022-3263

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Photochemical approach to the synthesis
✍ Maurizio D'Auria; Daniela Tofani πŸ“‚ Article πŸ“… 1992 πŸ› Elsevier Science 🌐 French βš– 778 KB

Three naturally occurring thienylacetylenes are synthesized through a photochemical coupling of S-iodo-2-thienyl derivatives and 5-~e~~~ylsilyl\_2\_te~lacetylene. Recently we have reported that the irradiation of S-iodothiophene-2-carbaldehyde (1) in the presence of 2~~~l~ophene (2) gave a mixtore