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Concerted and stepwise mechanisms in cycloaddition reactions: potential surfaces and isotope effects

โœ Scribed by Houk, Kendall N.; Li, Yi; Storer, Joey; Raimondi, Laura; Beno, Brett


Book ID
120231969
Publisher
Royal Society of Chemistry
Year
1994
Tongue
English
Weight
660 KB
Volume
90
Category
Article
ISSN
0956-5000

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Addition and Cycloaddition Reactions of
โœ Hartnagel, Manfred ;Grimm, Klaus ;Mayr, Herbert ๐Ÿ“‚ Article ๐Ÿ“… 1997 ๐Ÿ› John Wiley and Sons ๐ŸŒ English โš– 1002 KB

## Abstract Arenediazonium ions 1 undergo [2^+^ + 4] cycloadditions with (__E__)โ€1,3โ€pentadiene (2a), 2,3โ€dimethylbutadiene (2b), and (__E__)โ€2โ€methylโ€1,3โ€pentadiene (2c) to give dihydropyridazines or pyridazinium salts. While highly electrophilic diazonium ions and the unsymmetrical dienes 2a and