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Concerning the structure and fragmentation of [C3H7O]+ ions derived from alcohols

✍ Scribed by C. W. Tsang; A. G. Harrison


Publisher
John Wiley and Sons
Year
1971
Tongue
English
Weight
494 KB
Volume
5
Category
Article
ISSN
1076-5174

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MNDO study of fragmentations in mass spe
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## MNDO calculations of [C3H ,0]+' predict the parallel existence of both structures of radical cations of acetone (1) and propen-2-01 (2) in electron ionization spectra. The calculated heats of formation of 1+' (A@"Do = 783.2 kJ mol-' and of 2" (AflNDo = 649.8 kJ mol-') are in very good agreement