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Concerning the reaction of (η5-1-methoxycarbonylpentadienyl)(tricarbonyl)iron(+1) with malonate anion: a structural correction

✍ Scribed by William A. Donaldson; Muthukumar Ramaswamy


Book ID
104229612
Publisher
Elsevier Science
Year
1989
Tongue
French
Weight
145 KB
Volume
30
Category
Article
ISSN
0040-4039

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✦ Synopsis


The title reaction was originally reported to afford the E,Z-lj4-diene complex. Reexamination of the spectral data and decomplexation of the ligand indicates that the product is a d-x-ally1 complex.


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Reaction of cationic 1-substituted (η5-4
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Reaction of p-anisidine 13 or p-bromo orthoanisidine 14 with the new bi-deuterated dienyl complex 12 bearing a leaving group on its side chain affords the mono-deuterated 18a, 19a and the non-deuterated lgb and 19b spiro[1,2,3,4-tetrahydroquinoline-4,1'-cyclohexane] derivatives. The formation of the