A Stable and Recoverable Chiral Ru Lewis
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E. Peter Kündig; Christophe M. Saudan; Gérald Bernardinelli
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Article
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1999
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John Wiley and Sons
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English
⚖ 159 KB
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Ease of generation, stablity in solution at ambient temperature, high enantioselectivity in Diels-Alder reactions, efficient catalyst recovery, and large rate differences on variation of the anion are all characteristics of the new Ru Lewis acid [CpRu((S,S)-biphop-F)] (biphop-F=(C F ) POCH (Ph)CH (P