Concerning the mechanism of a cyanometallate mediated carbonylation reaction
β Scribed by R. del Rosario; L.S. Stuhl
- Publisher
- Elsevier Science
- Year
- 1982
- Tongue
- French
- Weight
- 243 KB
- Volume
- 23
- Category
- Article
- ISSN
- 0040-4039
No coin nor oath required. For personal study only.
β¦ Synopsis
The CN=(CN),(C~),~~-anion (I) reacts with either one or two equivalents of benzyl bromide in either water/acetone or anhydrous acetonltrile to produce mainly 1,3-diphenyl-2-propanone. Excess carbon monoxide in-hIbIts the reaction.
π SIMILAR VOLUMES
SQ4E time ago we described the reaction of dimethyloxosulfonium methylide (I) with certain carbonyl compounds to give oxiranes by methylene transfer
## Abstract **Summary:** The debate on the mechanism of dithiobenzoateβmediated RAFT polymerization may be resolved by including the reaction between a propagating radical and the starβshaped combination product from irreversible termination into the kinetic scheme. By this step, a highly reactive