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Concerning the Formation, Hydrolysis and Thermolysis of Acyclic Phosphoranes

โœ Scribed by Lowther, Nicholas; Crook, Polly; Hall, Dennis

Book ID
126527991
Publisher
Informa UK (Taylor & Francis)
Year
1987
Weight
189 KB
Volume
30
Category
Article
ISSN
0308-664X

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๐Ÿ“œ SIMILAR VOLUMES

The hydrolysis of phosphoranes in aqueou
The hydrolysis of phosphoranes in aqueous dioxane
โœ A. Queen; A. E. Lemire; A. F. Janzen ๐Ÿ“‚ Article ๐Ÿ“… 1981 ๐Ÿ› John Wiley and Sons ๐ŸŒ English โš– 247 KB

The entropy of activation for the hydrolysis of pentaphenoxyphosphorane in 25% aqueous dioxane is -188 J/mol deg. T h e enthalpy of activation is 22.5 kJ/mol, which is small for the relatively slow reaction. This suggests that the reaction is a multistep process having a preliminary equilibrium with