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Concentration enhancement of the vibronic transitions of the Pr3+ ion

✍ Scribed by C. de Mello Donegá; A. Ellens; A. Meijerink; G. Blasse

Publisher
Elsevier Science
Year
1993
Tongue
English
Weight
721 KB
Volume
54
Category
Article
ISSN
0022-3697

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Vibronic intensities in the optical abso
Vibronic intensities in the optical absorption spectra of Pr3+ in Cs2NaPrxY1−xCl6: concentration and temperature dependence
✍ Thomas Luxbacher; Harald P. Fritzer; Colin D. Flint 📂 Article 📅 1995 🏛 Elsevier Science 🌐 English ⚖ 341 KB

The 3H4~3P o transition in the absorption spectra of Pr 3+ in the hexachloroelpasolites Cs2NaPrxY~\_xCl6 (X=0.1 to x= 1 ) have been measured from 300 to 10 K. The electronic spectra are dominated by electric-dipole allowed vibronic origins enabled by Herzberg-Teller coupling. The two odd parity vibr