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Concentration effects in nucleophilic reactions of tertiary amines in aqueous solutions: The addition of amines to acrylamide monomers in the presence of hydrogen chloride

✍ Scribed by O. A. Kazantsev; D. S. Baruta; A. P. Sivokhin; K. V. Shirshin; D. M. Kamorin


Book ID
110185309
Publisher
International Academic Publishing Co (Nauka/Interperiodica)
Year
2011
Tongue
English
Weight
173 KB
Volume
85
Category
Article
ISSN
0036-0244

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## Abstract __tert__‐Butylsulfinyl chloride (**1**) reacts smoothly with __N__′‐(di)methyl‐ and __N__′‐(di)phenyl‐__N__‐hydroxyurea (**2**) in acetone at room temperature, in the presence of two equivalents of pyridine. An intermediate __O‐tert__‐butylsulfinyl‐__N__‐hydroxyurea (**3**) is postulate