Starting from the hydrodynamic continuity equation, the variation up to C 3/2 of the self-and tracer-diffusion coefficient in electrolytic solution was obtained for a supporting electrolyte whose mobilities are equal.
β¦ LIBER β¦
Concentration dependence of the self-diffusion coefficients of water in electrolyte solutions
β Scribed by A. M. Sazonov; V. M. Olevskii; A. B. Porai-Koshits; V. N. Skobolev; G. A. Shmuilovich
- Publisher
- SP MAIK Nauka/Interperiodica
- Year
- 1974
- Tongue
- English
- Weight
- 305 KB
- Volume
- 14
- Category
- Article
- ISSN
- 0022-4766
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## Abstract The freeβvolume theory of diffusion is used to predict the effect of the glass transition on the concentration dependence of the solvent selfβdiffusion coefficient at constant temperature. The theoretical prediction is in agreement with experimental data. Β© 2003 Wiley Periodicals, Inc.
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