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Computer simulation of network formation in free-radical crosslinking copolymerization

✍ Scribed by Hidetaka Tobita; Kenji Ito

Book ID
108043014
Publisher
Elsevier Science
Year
1994
Tongue
English
Weight
666 KB
Volume
2
Category
Article
ISSN
0966-7822

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## Abstract The topology of networks formed by radical crosslinking copolymerization is strongly dependent on the type of crosslinker chosen. By a series of computer simulations, the influence of the relative reactivities of crosslinker and monomer on the network properties was investigated. Basic

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## Abstract A new simulation model for network formation in free‐radical copolymerization of vinyl and divinyl monomers is proposed. This model is based on the crosslinking density distribution of the primary polymer molecules that results from a kinetically controlled network formation. The crossl