✦ LIBER ✦

Computer simulation of electron transfer reactions between two molecular species in solvents of various polarity

✍ Scribed by Maria Hilczer; M. Tachiya

Book ID: 104304093
Publisher: Elsevier Science
Year: 2000
Tongue: English
Weight: 362 KB
Volume: 86
Category: Article
ISSN: 0167-7322
DOI: 10.1016/s0167-7322(99)00130-0

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✦ Synopsis

Relation between fluorescence quenching via electron transfer (ET) and an exciplex formation for aromatic photoexcited acceptor -donor systems in solvents of different polarity at room temperature has been considered. Analysis was performed basis of potentials of mean force (PMF) for the ion pairs (IP) that arise due to charge separation. A distance dependence of the rate constants of the IP geminate recombination and dissociation in polar solvents has been discussed.

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