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Computational modeling of enzymatic keto-enol isomerization reactions

✍ Scribed by Isabella Feierberg; Johan Åqvist

Book ID
105885491
Publisher
Springer
Year
2002
Tongue
English
Weight
324 KB
Volume
108
Category
Article
ISSN
1432-2234

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📜 SIMILAR VOLUMES

Keto-to-enol isomerization in the molecu
Keto-to-enol isomerization in the molecular ion of dimethylmethylphosphonate
✍ James R. Holtzclaw; Jeffrey R. Wyatt 📂 Article 📅 1988 🏛 John Wiley and Sons 🌐 English ⚖ 590 KB

A mechanism for keto-to-enol isomerization in dimethylmethylphosphonate (DMMP) has been proposed based on deuterium-labeling studies, a model compound and thermodynamic data. An electron ionization study of H/D exchange occurring in CD,-labeled D M M P suggests that rapid keto-to-enol isomerization