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Computation of intensities of vibrational spectra of electronic bands in diatomic molecules III

โœ Scribed by Anees Rahman

Publisher
Elsevier Science
Year
1955
Weight
177 KB
Volume
21
Category
Article
ISSN
0031-8914

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โœฆ Synopsis

Following the technique of M a n n e b a c k 1) which provides very simple recurrence relations for the calculation of transition moments, it is shown that similar recurrence relations give the transition moments also when the purely electronic transition probability varies exponentially with the internuclear distance. The usefulness of the recurrence relations is demonstrated by computing the matrix of transition moments for the A ~-~ X transition of the molecule OH.

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๐Ÿ“œ SIMILAR VOLUMES

Computation of intensities of vibrationa
Computation of intensities of vibrational spectra of electronic bands in diatomic molecules. II
โœ C. Manneback; A. Rahman ๐Ÿ“‚ Article ๐Ÿ“… 1954 ๐Ÿ› Elsevier Science โš– 202 KB

Following up the technique of M a n n e b a c k 1) which provides very simple recurrence relations for the calculation of transition-moments, similar recurrence relations are now developed showing that if electrical anharmonicity is introduced while conserving the mechanical harmonicity of the two e