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Compton profiles and polarizability as two similar probes of the electronic structure of 14 electron diatomic molecules: An ab initio study

✍ Scribed by Mohammadou Mérawa; Michel Rérat; Albert Lichanot


Publisher
John Wiley and Sons
Year
1999
Tongue
English
Weight
242 KB
Volume
71
Category
Article
ISSN
0020-7608

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✦ Synopsis


High-and low-energy scattering properties, namely, Compton profiles Ž . and polarizability, respectively, were calculated at the configuration interaction CI level Ž . from molecular orbitals expressed in the linear combination of atomic orbitals LCAO model for 14 electron diatomic molecules. Extended atomic basis sets including about 100 Ž . Gaussian-type functions GTFs were used. The isotropic and directional Compton profiles and the polarizability show that the behavior of CO and N is rather similar but 2 very different from that of BF.