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Compression factors and second virial coefficients of CO2, CO, and {xCO+ (1 − x)CO2}

✍ Scribed by B.V Mallu; G Natarajan; D.S Viswanath

Publisher
Elsevier Science
Year
1987
Tongue
English
Weight
314 KB
Volume
19
Category
Article
ISSN
0021-9614

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✦ Synopsis

An isochoric-isothermal

Burnett apparatus was used to measure the (p, V,. 7') values of CO,.

CO, and (0.4268CO + OS732C0,). Measurements were made in the temperature range 323 to 423 K and pressures up to 6.5 MPa. The experimental results were appropriately treated to extract compression factors and second virial coefficients.

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✍ Peter J. McElroy; Josef Moser 📂 Article 📅 1995 🏛 Elsevier Science 🌐 English ⚖ 296 KB

The excess second virial coefficient of (0.500CO + 0.500CO2)(g) has been determined at temperatures 303.15 K, 313.14 K, 323.15 K, 333.15 K, and 343.15 K. The pressure-change-ofmixing method was used. The excess molar enthalpy was derived as well as unlike-interaction second virial coefficients which