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Comprehensive Investigation of Catalyst Structure and Polymerization Conditions for Chain Branching in Ethylene Polymerization with Phillips-Type Catalysts

✍ Scribed by Kiwamu Tonosaki; Toshiaki Taniike; Minoru Terano


Book ID
112147262
Publisher
John Wiley and Sons
Year
2011
Tongue
English
Weight
335 KB
Volume
5
Category
Article
ISSN
1862-832X

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Studies of Ziegler-type catalysts for th
✍ E.W. Duck; D. Grant; J.R. Horder; D.K. Jenkins; A.E. Marlow; S.R. Wallis; A.G. D πŸ“‚ Article πŸ“… 1974 πŸ› Elsevier Science 🌐 English βš– 626 KB

VOCla-Et3A12Cl 3 (chlorinated activator) catalysts have been employed for the polymerization of ethylene at T between 15 and 85 Β° in n-hexane. Using butylperchlorocrotonate as the activator, the following catalyst efficiencies (g polymer/gV, hr, atmosphere ethylene in the cap gas) were achieved: l06