Our interest in benzenediol formation was initiated by the isolation and identification of 2,5-dimethyl-1,4\\_benzenediol from the liquefaction product of cellulose\\*. During that work, 2,5-dimethyl-2,5-cyclohexadiene-1,4-dione (l), 2,3butanedione (biacetyl), and 3-hydroxy-2-butanone (acetoin) were
Comprehensive Cellulose Chemistry Volume 2 || Systematics of Cellulose Functionalization: Section 4.5–4.5.1
✍ Scribed by Klemm, D.; Philipp, B.; Heinze, T.; Heinze, U.; Wagenknecht, W.
- Book ID
- 120090574
- Publisher
- Wiley
- Year
- 1998
- Weight
- 632 KB
- Volume
- 10.1002/3527601937
- Category
- Article
- ISBN-13
- 9783527601936
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## Abstract The synthesis of new spiro derivatives of tetrahydro‐2‐benzazepine was accomplished and their nitration, bromination, allylation, acetylation, formylation and oxidation reactions were studied. Nitration and bromi‐nation of 5‐methyl(1,5‐dimethyl)‐1,2,4,5‐tetrahydrospiro[3__H__‐2‐benzazep
Chemistry of Functionalized Benzazepines. Part 5. Synthesis and Chemical Transformation of the 1,2,4,5-Tetrahydrospiro[3H-2benzazepine-3,1'-cycloalkanes]. -A number of new spiroderivatives of tetrahydro-2-benzazepine (III) are synthesized by reaction of imines (I) with allyl Grignard reagent (II)