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Compounds of titanium(III) chloride from nonaqueous solvents

✍ Scribed by McDonald, Guy D.; Thompson, Megan; Larsen, Edwin M.

Book ID
127193915
Publisher
American Chemical Society
Year
1968
Tongue
English
Weight
965 KB
Volume
7
Category
Article
ISSN
0020-1669

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The equilibrium quotients for the formation of Co(NH3) SCl2+ from Co(NH3) 50Hz3+ and CI1were 3.74 f 0.25 M-' and 6.07 f 0.54 M-' at 45.OoC in 10: 1 mole ratio water: dimethyl sulfoxide and in 25 w/w yo aqueous ethanol, respectively, and those for the formation ofthe ion pair C O ( N H ~) ~O H ~~+ .