The 147 nm (8.4 eV) photolysis of gaseous C2H51, n-C3H71, and sec-C3H71 was investigated in the presence of and absence of HI. The main overall processes are: These dissociative processes occur mainly as a result of initial cleavage of the weak C-1 bond, followed by decomposition of the internally
✦ LIBER ✦
Composition of the CnH2n−8fraction from an alkylation reaction
✍ Scribed by P. W. Flanagan; M. C. Hamming; F. M. Evens
- Book ID
- 112934236
- Publisher
- Springer-Verlag
- Year
- 1967
- Tongue
- English
- Weight
- 969 KB
- Volume
- 44
- Category
- Article
- ISSN
- 0003-021X
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## Abstract A new PPh~3~‐catalyzed synthesis of alkyl 2‐[aryl(tosylimino)methyl]acrylates from propiolate and __N__‐tosylimine has been developed. Deuterium‐labelling experiments show that the reaction mechanism involves several hydrogen‐transfer processes, which are not the turnover‐limiting step