A new synthesis of spirobenzylisoquinoli
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Herbert L. Holland; David B. MacLean; Russell G.A. Rodrigo; Richard F.H. Manske
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Article
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1975
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Elsevier Science
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French
โ 152 KB
The reduction product of dehydrocordrastine, 2, with di-isobutylaluminum hydride spontaneously rearranged to the spirobenzylisoquinolines 7a and 7b, analogous to the alkaloids hr ry sibiricine (5a), corydaine (21, and yenhusomidine (2). ## N Previous syntheses (1) of spirobenzylisoquinline alkalo