Complexing behaviour of D(+)-1,2-bis(4-phenyl-1,2,4-triazoline-5-thione-3-yl)ethylene glycol with iron(III), nickel(II), copper(II), zinc(II) and mercury(II)
✍ Scribed by Vishnu J. Ram; Lallan Mishra; Hirdya N. Pandey
- Publisher
- Springer
- Year
- 1979
- Tongue
- English
- Weight
- 180 KB
- Volume
- 4
- Category
- Article
- ISSN
- 0340-4285
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Fe m, Co n, Ni u and CH ll complexes of a new Schiff base, 2-phenyl-1,2,3-triazole-4-carboxalidene-2-aminophenol (PTCAP), have been synthesized and characterized by elemental analyses, molar conductance and magnetic susceptibility measurements, and by u.v.-vis., i.r. and e.p.r. spectral observations
## Abstract 1,2,4‐Triphenyl‐1,3,5‐triazapentadiene (1a), prepared from benzamidine and __N__‐phenylbenzimidoyl chloride, was treated at room temperature with CoCl~2~, Ni(NO~3~)~2~, Na~2~PdCl~4~, CuCl~2~ and ZnCl~2~ to form the corresponding six‐membered 1:1 chelate complexes 1a·CoCl~2~, 1a·Ni(NO~3~