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Compleximetric titration of chromium (III) with catalytic end-point detection

โœ Scribed by Siegbert Pantel


Publisher
Elsevier Science
Year
1987
Tongue
English
Weight
147 KB
Volume
203
Category
Article
ISSN
0003-2670

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โœฆ Synopsis


Chromium (III) (2-20 mg) is determined by reaction with excess of EDTA and backtitration with a standard copper (II) solution to a catalytic end-point. The indicator reaction is the copper (II) -catalyzed autodecomposition of hydrogen peroxide, which is observed biamperometrically. For 10 mg of chromium (III), the relative standard deviation was < 0.5% (n= 10).


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## Abstract A sensitive, rapid and inexpensive capillary electrophoretic method for the determination of Cr(III) and Cr(VI) species is presented. The method is based on the dual opposite end injection principle and contactless conductometric detection. The sample containing cationic and anionic spe