Compleximetric titration of chromium (III) with catalytic end-point detection
โ Scribed by Siegbert Pantel
- Publisher
- Elsevier Science
- Year
- 1987
- Tongue
- English
- Weight
- 147 KB
- Volume
- 203
- Category
- Article
- ISSN
- 0003-2670
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โฆ Synopsis
Chromium (III) (2-20 mg) is determined by reaction with excess of EDTA and backtitration with a standard copper (II) solution to a catalytic end-point. The indicator reaction is the copper (II) -catalyzed autodecomposition of hydrogen peroxide, which is observed biamperometrically. For 10 mg of chromium (III), the relative standard deviation was < 0.5% (n= 10).
๐ SIMILAR VOLUMES
## Abstract A sensitive, rapid and inexpensive capillary electrophoretic method for the determination of Cr(III) and Cr(VI) species is presented. The method is based on the dual opposite end injection principle and contactless conductometric detection. The sample containing cationic and anionic spe