Complexes with a Metal—Phosphorus Triple Bond as Versatile Building Blocks in Coordination and Organometallic Chemistry

Tetra- and Octalactam Macrocycles and Ca

Tetra- and Octalactam Macrocycles and Catenanes with Exocyclic Metal Coordination Sites: Versatile Building Blocks for Supramolecular Chemistry

✍ Xi-you Li; Jens Illigen; Martin Nieger; Steffen Michel; Christoph A. Schalley 📂 Article 📅 2003 🏛 John Wiley and Sons 🌐 English ⚖ 450 KB 👁 3 views

## Abstract The synthesis of a new tetralactam macrocycle and the simultaneous formation of catenanes and larger octalactam macrocycles is reported. These species bear 2,2′‐biquinoline moieties suitably positioned to bind a metal center at the outer periphery of the macrocycles. ^1^H NMR chemical s