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Complexes of Manganese, Iron, Zinc, and Molybdenum with a Superbasic Tris(guanidine) Derivative of Tris(2-ethylamino)amine (Tren) as a Tripod Ligand

✍ Scribed by Harald Wittmann; Volker Raab; Andrea Schorm; Jörn Plackmeyer; Jörg Sundermeyer


Publisher
John Wiley and Sons
Year
2001
Tongue
English
Weight
520 KB
Volume
2001
Category
Article
ISSN
1434-1948

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The synthesis and structural characterization of manganese, iron, and cobalt complexes of bis[di(2-pyridyl)methyl]amine (bdpma) were investigated. The bdpma ligand can give rise to mono-or dimeric complexes. Moreover, bdpma can undergo oxidative degradation leading to 1,3,3-tris(2-pyridyl)-3Himidazo