Complexes of lanthanoid salts with macrocyclic ligands. Part 25. Lanthanoid trifluoroacetate complexes with 12-crown-4, 15-crown-5, and 18-crown-6 ethers
β Scribed by Jean-Claude G. Bunzli; Aldo Giorgetti
- Book ID
- 108324245
- Publisher
- Elsevier Science
- Year
- 1985
- Tongue
- English
- Weight
- 997 KB
- Volume
- 110
- Category
- Article
- ISSN
- 0020-1693
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π SIMILAR VOLUMES
Complexes between the heavier lanthanoid nitrates Ln(NO~3~)~3~ and 15βcrownβ5 (**1**) and 18βcrownβ6 (**2**) ethers were isolated and characterized. Both 1:1 and 4:3 complexes are formed with each Ln(III) ion, except in the case of Gd and **2**. The thermal transformation of the 1:1 complexes into t
## Abstract Complexes of lanthanoid trinitrates Ln(NO~3~)~3~ with 15βcrownβ5 ether **1** (Ln = La, Ce, Pr, Nd, Sm, Eu, Gd) and with 18βcrownβ6 ether **2** (Ln = La, Ce, Pr, Nd) having a 1:1 stoichiometry as well as 4:3 complexes with **2** (Ln = La, Ce, Pr, Nd, Sm, Eu, Gd) have been synthesized and