Complexes of HNO3 and NO3− with NO2 and N2O4, and their potential role in atmospheric HONO formation
✍ Scribed by Kamboures, Michael A.; Raff, Jonathan D.; Miller, Yifat; Phillips, Leon F.; Finlayson-Pitts, Barbara J.; Gerber, R. Benny
- Book ID
- 120448972
- Publisher
- Royal Society of Chemistry
- Year
- 2008
- Tongue
- English
- Weight
- 432 KB
- Volume
- 10
- Category
- Article
- ISSN
- 1463-9076
- DOI
- 10.1039/b805330h
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## Abstract The oxidation of copper, zinc and nickel by N~2~O~5~ led, respectively, to turquoise‐coloured single crystals of (NO)Cu(NO~3~)~3~ [monoclinic, __P__2~1~/__m__, __Z__ = 2, __a__ = 465.90(5), __b__ = 1111.7(1), __c__ = 700.7(1) pm, __β__ = 100.70(2)°, __wR__~2~ = 0.0566], light‐yellow sin
Metal Oxidation with N 2 O 5 : The Nitrosylium Nitrates (NO)Cu(NO 3 ) 3 , (NO)2[Zn(NO3)4] and (NO)6[Ni4(NO3)12](NO3)2•(HNO3). -N2O5 is prepared by reaction of fuming HNO3 with P4O10 and directly condensed on the metal powders. The crystal structures of the resulting title compounds are determined by