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Complexes of Crown Ethers with Uronium Salts: Preparation and Crystal Structure of [18]Crown-6 Uronium Nitrate (1/1) and Benzo[27]crown-9 Uronium Perchlorate (1/1)

✍ Scribed by Drs. Jos W. H. M. Uiterwijk; Dr. Sybolt Harkema; Prof. Dr. ir. David N. Reinhoudt; Dr. Kari Daasvatn; Dr.; Jr. Herman J. den Hertog; Jan Geevers

Publisher
John Wiley and Sons
Year
1982
Tongue
English
Weight
209 KB
Volume
21
Category
Article
ISSN
0044-8249

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Solution and Solid-State Preparation of
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## Abstract 18‐Crown[6] ether has been used to prepare a new class of organic–inorganic complexes of general formula 18‐crown[6]β‹…M[HSO~4~]~__n__~ (where M = NH~4~^+^, K^+^, Sr^2+^ and __n__ = 1, 2) by reacting directly in solution or in the solid state the crown ether 18‐crown[6] with inorganic sal