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Complexes of Boron Trifluoride with Amides

โœ Scribed by Muetterties, Earl L.; Rochow, Eugene G.


Book ID
127050973
Publisher
American Chemical Society
Year
1953
Tongue
English
Weight
295 KB
Volume
75
Category
Article
ISSN
0002-7863

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## The successful isolation of NiL(CO13 and NiLa-(CO) (L = Me@PFJ is reported. Boron tn'fluoride reacts with NiL2(CO)2 to yield NiL,(CO)2*nBF3, where n = 1.44 at -128 'Cand I.11 at 2 "C, and with NiL4 to yield NiL.,*nBF,, where n = 2.6 at -100 "C, n = 1.78 at -3 "C and n = 1.24 at +20 "C. Nuclear ma