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Complexes of biologically important ligands. I. Ternary complexes of nickel(II) comprising 1,10-o-phenanthrolineazosulfonamide derivatives and alkyldithiophosphates

✍ Scribed by A. A. M. Aly; I. M. A. Awad; M. Abd El-Mottaleb; K. Abd El-Aal


Book ID
111490952
Publisher
Versita
Year
2006
Tongue
English
Weight
209 KB
Volume
60
Category
Article
ISSN
0366-6352

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✦ Synopsis


Abstract

5-[p-(R-Sulfonyl)phenylazo]-1,10-o-phenanthroline (L) and its octahedral complexes of the type [Ni(R2dtp)2(L)] (where R2dtp = diethyl-or dipropyldithiophosphate) with the core NiN2S4 have been prepared and characterized by spectral, magnetic, and thermogravimetric methods. The thermal decomposition mechanism of the compounds was proposed and the kinetic parameters of decomposition were calculated making use of the Coatsβ€”Redfern and Horowitzβ€”Metzger equations.


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