Complexes and Clusters of Water Relevant to Atmospheric Chemistry: H2O Complexes with Oxidants
β Scribed by Petr G. Sennikov; Stanislav K. Ignatov; Otto Schrems
- Publisher
- John Wiley and Sons
- Year
- 2005
- Tongue
- English
- Weight
- 682 KB
- Volume
- 6
- Category
- Article
- ISSN
- 1439-4235
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## Abstract The treatment of [M(ΞΌβCl)(coe)~2~]~2~ (M = Rh, Ir; coe = cyclooctene) with the Ξ±βdiketimines ArN=C(Me)C(Me)=NAr (Ar = Ph, Xy; Xy = 2,6βMe~2~C~6~H~3~) in thf, followed by the addition of CN__t__Bu, gave the Ξ±βdiketimine complexes [M(Cl){ArN=C(Me)C(Me)=NAr} (CN__t__Bu)] (1: M = Rh, Ar = P
Much attention has been paid to the oxidation of water to dioxygen by homogeneous catalysts. Of particular interest are di-and tetranuclear transition metal complexes, since extended X-ray absorption fine structure studies have indicated that the O 2 -evolving center (OEC) in photosystem II is compo