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Complexations of 13-group metalsIII with 7-[(2-hydroxy-5-chlorophenyl)azo]-8-hydroxyquinoline-5-sulfonate

✍ Scribed by Longhe Piao; Fumiaki Kai; Masaaki Hirohata


Publisher
Elsevier Science
Year
1997
Tongue
English
Weight
404 KB
Volume
16
Category
Article
ISSN
0277-5387

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The configurations and conformations of 5.1 S-dialkyloctaethylporphodimethenes HdOEPRd are described for R = Me. Et, iPr, tBu. The "normal" compounds (1 a to ld) have the syn-axial ("au") configuration, the %nomalous" isomers (2b to 4b) the anti configuration at CS.15. This is proved by a crystal st