Complexation with Diol Host Compounds, 12. Synthesis and Solid-State Inclusion Properties of Bis(diarylhydroxymethyl)1-Substituted 1,1′-Binaphthyls. Crystal Structures of a Host and Its Pyridine Clathrate
✍ Scribed by Weber, Edwin ;Skobridis, Konstantinos ;Wierig, Andreas ;Barbour, Leonard J. ;Caira, Mino R. ;Nassimbeni, Luigi R.
- Publisher
- Wiley (John Wiley & Sons)
- Year
- 1993
- Tongue
- English
- Weight
- 806 KB
- Volume
- 126
- Category
- Article
- ISSN
- 0009-2940
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✦ Synopsis
Diol host compounds / Clathrates / Crystal structures of host and clathrate / 1,l'-Binaphthyl derivatives A series of new clathrate host molecules 1-8 containing two bis(diarylhydroxymethy1) groups attached to different positions (2,2' or 8 , 8 ) of a 1,l'-binaphthyl frame have been synthesized. Their clathrate formation properties with organic guests including alcohols, amines, ketones, and other dipolar aprotic compounds or aromatic hydrocarbons are reported (74 examples of clathrates) together with the results of solvent competition experiments for the parent host compound. The inclusion formation and the clathrate stoichiometries depend on the structure of the host molecules in a systematic manner. The crystal structures of the free parent host 1 and its pyridine